[μ-1,2-Bis(diphenylphosphanyl)benzene-κ2 P:P′]bis[chloridogold(I)]
نویسندگان
چکیده
In the crystal structure of the non-solvate form of the title compound, [Au(2)Cl(2)(C(30)H(24)P(2))], two almost linear P-Au(I)-Cl units [175.87 (3) and 171.48 (3)°] are in a skewed arrangement with a Cl-Au⋯Au-Cl torsion angle of -65.29 (3)° so as to form an intra-molecular Au⋯Au inter-action [3.0563 (2) Å]. The complex mol-ecules are connected each other through inter-molecular C-H⋯π inter-actions, giving a sheet structure parallel to the bc plane.
منابع مشابه
{μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-dimethylhydrazine-κ2 P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(30)H(34)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two almost linearly coordinated gold(I) atoms [P-Au-Cl = 175.68 (3) Å]. The nuclei are 3.122 (2) Å apart. The mol-ecule exhibits a twofold rotation axis.
متن کامل[μ-1,2-Bis(diphenylphosphanyl)-1,2-diethylhydrazine-κ2 P:P′]bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(28)H(30)N(2)P(2))]·2C(4)H(8)O, was synthesized from a bidentate phosphine ligand complexed to two linear gold(I) chloride moieties. The Au(I) atom is in an almost linear coordination with a P-Au-Cl angle of 179.22 (4)°. The complex molecules reside on a twofold rotation axis.
متن کامل[μ-1,2-Bis(diphenylphosphanyl)-1,2-dimethylhydrazine-κ2 P:P′]bis[chloridogold(I)]
The title compound, [Au(2)Cl(2)(C(26)H(26)N(2)P(2))], is formed from a bidentate phosphine ligand complexed to two linearly coordinated gold(I) atoms. The gold(I) atoms are 3.4873 (7) Å apart. The mol-ecule exhibits a crystallographic twofold rotation axis.
متن کامل{μ-1,2-Bis[bis(4-methoxyphenyl)phosphanyl]-1,2-diethylhydrazine-κ2 P:P′}bis[chloridogold(I)] tetrahydrofuran disolvate
The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P-Au-Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The mol-ecule exhibits a twofold symmetry axis. Stacks of the compound are formed through inter-molecular C-H⋯Cl inter-actions, while the tetra-hydro-furan (THF) solvate is further atta...
متن کامل{μ-trans-N,N′-Bis[(diphenylphosphanyl)methyl]benzene-1,4-diamine-κ2 P:P′}bis{(acetonitrile-κN)[dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5]copper(I)} bis(tetrafluoridoborate)
In the centrosymmetric dinuclear title compound, [Cu(2)(C(2)H(3)N)(2)(C(18)H(10)N(4))(2)(C(32)H(30)N(2)P(2))](BF(4))(2), the Cu(I) centre is coordinated by two N atoms from a dipyridophenazine ligand, one P atom from an N,N'-bis-[(diphenyl-phosphan-yl)meth-yl]benzene-1,4-diamine (bpbda) ligand, and one N atom from an acetonitrile mol-ecule in a distorted tetra-hedral geometry. The bpbda ligand,...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2010